To really get an accurate reading, you need to buy a conductivity meter. Most TDS meters are not really accurate and can change from brands.
Reject water is commonly used with cool down arches on conveyors, side blasters, underbody flush (love when they used to call them bottom blasters, and sometimes rinsing after the wash process before trifoams or sealants.
Soft water will give lower TDS output and will help the membranes last longer.
Check the RO product straight from the machine and at the arch, not the reject. That will tell you whether the product is getting contaminated somewhere to account for the different numbers between the machine and the reading at the arch.